| Viernes 9 de septiembre de 2022: | |||||
| Girona | – | Valladolid | 2 | – | 1 |
| Sábado 10 de septiembre de 2022: | |||||
| Rayo Vallecano | – | Valencia | 2 | – | 1 |
| Espanyol | – | Sevilla | 2 | – | 3 |
| Cadiz | – | Barcelona | 0 | – | 4 |
| Atlético de Madrid | – | Celta de Vigo | 4 | – | 1 |
| Domingo 11 de septiembre de 2022: | |||||
| Real Madrid | – | RCD Mallorca | 4 | – | 1 |
| Elche | – | Athletic de Bilbao | 1 | – | 4 |
| Getafe | – | Real Sociedad | 2 | – | 1 |
| Betis | – | Villarreal | 1 | – | 0 |
| Lunes 12 de septiembre de 2022: | |||||
| – | Osasuna | 19:00 | |||
| EQUIPO | J | G | E | P | Goles | Pts | |
| 1. | Real Madrid | 5 | 5 | 0 | 0 | 15-5 | 15 |
| 2. | Barcelona | 5 | 4 | 1 | 0 | 15-1 | 13 |
| 3. | Betis | 5 | 4 | 0 | 1 | 8-3 | 12 |
| 4. | Villarreal | 5 | 3 | 1 | 1 | 9-1 | 10 |
| 5. | Athletic de Bilbao | 5 | 3 | 1 | 1 | 9-2 | 10 |
| 6. | Atlético de Madrid | 5 | 3 | 1 | 1 | 9-4 | 10 |
| 7. | Osasuna | 4 | 3 | 0 | 1 | 6-3 | 9 |
| 8. | Celta de Vigo | 5 | 2 | 1 | 2 | 8-10 | 7 |
| 9. | Rayo Vallecano | 5 | 2 | 1 | 2 | 5-5 | 7 |
| 10. | Real Sociedad | 5 | 2 | 1 | 2 | 5-7 | 7 |
| 11. | Girona | 5 | 2 | 1 | 2 | 6-5 | 7 |
| 12. | Valencia | 5 | 2 | 0 | 3 | 7-5 | 6 |
| 13. | RCD Mallorca | 5 | 1 | 2 | 2 | 5-7 | 5 |
| 14. | Valladolid | 5 | 1 | 1 | 3 | 3-10 | 4 |
| 15. | Sevilla | 5 | 1 | 1 | 3 | 6-10 | 4 |
| 16. | 4 | 1 | 1 | 2 | 4-5 | 4 | |
| 17. | Getafe | 5 | 1 | 1 | 3 | 4-12 | 4 |
| 18. | Espanyol | 5 | 1 | 1 | 3 | 6-10 | 4 |
| 19. | Elche | 5 | 0 | 1 | 4 | 2-13 | 1 |
| 20. | Cadiz | 5 | 0 | 0 | 5 | 0-14 | 0 |
