| Viernes 7 de octubre de 2022: | |||||
| Osasuna | – | Valencia | 1 | – | 2 |
| Sábado 8 de octubre de 2022: | |||||
| Almería | – | Rayo Vallecano | 3 | – | 1 |
| Atlético de Madrid | – | Girona | 2 | – | 1 |
| Sevilla | – | Athletic de Bilbao | 1 | – | 1 |
| Getafe | – | Real Madrid | 0 | – | 1 |
| Domingo 9 de octubre de 2022: | |||||
| Valladolid | – | Betis | 0 | – | 0 |
| Cadiz | – | Espanyol | 2 | – | 2 |
| Real Sociedad | – | Villarreal | 1 | – | 0 |
| Barcelona | – | Celta de Vigo | 1 | – | 0 |
| Lunes 10 de octubre de 2022: | |||||
| Elche | – | RCD Mallorca | 19:00 | ||
| EQUIPO | J | G | E | P | Goles | Pts | |
| 1. | Barcelona | 8 | 7 | 1 | 0 | 20-1 | 22 |
| 2. | Real Madrid | 8 | 7 | 1 | 0 | 19-7 | 22 |
| 3. | Athletic de Bilbao | 8 | 5 | 2 | 1 | 17-5 | 17 |
| 4. | Atlético de Madrid | 8 | 5 | 1 | 2 | 14-7 | 16 |
| 5. | Real Sociedad | 8 | 5 | 1 | 2 | 13-11 | 16 |
| 6. | Betis | 8 | 5 | 1 | 2 | 10-5 | 16 |
| 7. | Valencia | 8 | 4 | 1 | 3 | 14-8 | 13 |
| 8. | Osasuna | 8 | 4 | 1 | 3 | 9-8 | 13 |
| 9. | Villarreal | 8 | 3 | 3 | 2 | 10-3 | 12 |
| 10. | Rayo Vallecano | 8 | 3 | 1 | 4 | 10-12 | 10 |
| 11. | Celta de Vigo | 8 | 3 | 1 | 4 | 9-14 | 10 |
| 12. | RCD Mallorca | 7 | 2 | 2 | 3 | 6-8 | 8 |
| 13. | Valladolid | 8 | 2 | 2 | 4 | 6-13 | 8 |
| 14. | Girona | 8 | 2 | 1 | 5 | 11-14 | 7 |
| 15. | Almería | 8 | 2 | 1 | 5 | 7-12 | 7 |
| 16. | Getafe | 8 | 2 | 1 | 5 | 8-16 | 7 |
| 17. | Sevilla | 8 | 1 | 3 | 4 | 8-14 | 6 |
| 18. | Espanyol | 8 | 1 | 3 | 4 | 11-16 | 6 |
| 19. | Cadiz | 8 | 1 | 2 | 5 | 3-16 | 5 |
| 20. | Elche | 7 | 0 | 1 | 6 | 3-18 | 1 |
