| Viernes 14 de octubre de 2022: | |||||
| Rayo Vallecano | – | Getafe | 0 | – | 0 |
| Sábado 15 de octubre de 2022: | |||||
| Girona | – | Cadiz | 1 | – | 1 |
| Valencia | – | Elche | 2 | – | 2 |
| RCD Mallorca | – | Sevilla | 0 | – | 1 |
| Athletic de Bilbao | – | Atlético de Madrid | 0 | – | 1 |
| Domingo 16 de octubre de 2022: | |||||
| Celta de Vigo | – | Real Sociedad | 1 | – | 2 |
| Real Madrid | – | Barcelona | 3 | – | 1 |
| Espanyol | – | Valladolid | 1 | – | 0 |
| Betis | – | Almería | 3 | – | 1 |
| Lunes 17 de octubre de 2022: | |||||
| Villarreal | – | Osasuna | 19:00 | ||
| EQUIPO | J | G | E | P | Goles | Pts | |
| 1. | Real Madrid | 9 | 8 | 1 | 0 | 22-8 | 25 |
| 2. | Barcelona | 9 | 7 | 1 | 1 | 21-4 | 22 |
| 3. | Atlético de Madrid | 9 | 6 | 1 | 2 | 15-7 | 19 |
| 4. | Real Sociedad | 9 | 6 | 1 | 2 | 15-12 | 19 |
| 5. | Betis | 9 | 6 | 1 | 2 | 13-6 | 19 |
| 6. | Athletic de Bilbao | 9 | 5 | 2 | 2 | 17-6 | 17 |
| 7. | Valencia | 9 | 4 | 2 | 3 | 16-10 | 14 |
| 8. | Osasuna | 8 | 4 | 1 | 3 | 9-8 | 13 |
| 9. | Villarreal | 8 | 3 | 3 | 2 | 10-3 | 12 |
| 10. | Rayo Vallecano | 9 | 3 | 2 | 4 | 10-12 | 11 |
| 11. | Celta de Vigo | 9 | 3 | 1 | 5 | 10-16 | 10 |
| 12. | Sevilla | 9 | 2 | 3 | 4 | 9-14 | 9 |
| 13. | RCD Mallorca | 9 | 2 | 3 | 4 | 7-10 | 9 |
| 14. | Espanyol | 9 | 2 | 3 | 4 | 12-16 | 9 |
| 15. | Girona | 9 | 2 | 2 | 5 | 12-15 | 8 |
| 16. | Valladolid | 9 | 2 | 2 | 5 | 6-14 | 8 |
| 17. | Getafe | 9 | 2 | 2 | 5 | 8-16 | 8 |
| 18. | Almería | 9 | 2 | 1 | 6 | 8-15 | 7 |
| 19. | Cadiz | 9 | 1 | 3 | 5 | 4-17 | 6 |
| 20. | Elche | 9 | 0 | 3 | 6 | 6-21 | 3 |
